LongRunner wrote:So to say polys are more heat-tolerant than conventional electrolytics isn't totally correct. Let's say you compare Panasonic FR with Chemi-con PSA (admittedly quite an old polymer series). Sure you need three 2200µF 6.3V FRs to match a single 470µF 6.3V PSA, but PSA is only rated for 2,000 hours at 105°C and FR from 10D x 20L on up is rated for 10,000 hours at the same temperature. So if you did, following the rules of thumb would give you this:
The endurance test isn't a wear out test. It's just an industry standard test. It is not the be all end all of capacitor lifetimes. Manufactures don't actually publish those. What -can- be said is aqueuous electrolyte expands much quicker and dries up much faster, especially with added heat, than non-aqueuous electrolyte does (electrolyte that still uses organic solvent of sorts in the form or quaternary ammomium salt compounds but that is much more resistant to heat, even if not quite as resistant as truly conductive and solid polymers).
The cross-over point is a bit under 75°C. But as stated, it isn't at all a fair comparison, as when Chemi-con PSA was new it wouldn't have been competing with Panasonic FR over motherboard VRMs - it would have been competing with the ultra-low-ESR electrolytics (Nichicon HM/HN, Rubycon MBZ/MCZ, Panasonic FJ/FL, Suncon (originally branded Sanyo) WG), which were rated for only 2,000 hours at 105°C. (Now that polys are no longer the expense they once were, it's not even worth making those. No one is interested in electrolytics with a low endurance rating and few other redeeming features.)
Again, those are only industry standard tests that expressly state the capacitor series in question will last -at least- this long at a certain temperature, at maximum ripple rating, and at 105*C, at a switching frequency of either 100KHz (105*C and low ESR capacitors) or 120Hz (85*C or general purpose capacitors), with the ESR rating stated at either 20*C or 25*C and -10*C respectively as those would be the temperatures the capacitors were restored back down to. It is never stated that they fail after those amount of hours. True conductive solid polymers at least don't have any liquid to dry out in them at all. Hybrid/functional polymers have very little water in them. Organic polymers are more of a cross between electrolytics and true polymers, but can still vent and bulge just like electrolytics with liquid in them, hence the safety vents. Also interesting about the 10*C drop = 2x the life is that in the KZG datasheet, Chemi-con state that for every 5*C the life is doubled... that also sets in stone, at least IMO, despite the fact that KZG is a crap series, that aqueous electrolyte is definitely more sensitive to heat. Also, the test conditions and prerequisites the endurance lifetimes have to conform to are rather loose - 200% or less of the dissipation value (ESR).
[*]Gradual demagnetisation of the recording layers (definitely affected by heat, but to what degree???)
That's a huge one. Hard drives a very fragile devices and are not meant to be abused, though admittedly at this point are somewhat dated technology. The platters expand and contract with even somewhat rapid temperature increases and drops, and that leads to their wear out quicker than not.
I don't know what effect temperature would have on the heads, short of them becoming so hot they can't operate until they cool down (as sometimes happens in minor head crashes that don't outright destroy the heads).
Head crashes are definitely another potential problem.